Cayenne was used by Native Americans as a pain reliever and to halt infections. It was also used for toothache, arthritis and to aid digestion. This herb has anti-bacterial properties, can stimulate blood flow and is rich in vitamins, minerals and antioxidants. Many people consume cayenne to maintain cardiovascular health. Studies suggest that it may be able to reduce triglyceride levels and platelet aggregation in the blood.
Cannabis is a controversial subject, and really needs an article all itself. Few people understand all the political and therapeutic issues surrounding cannabis. Many people distinguish between “medical cannabis” and “marijuana.” Medical cannabis involves research into particular varieties of the cannabis plant and its therapeutic value. Many varieties are lower in THC, the component that makes people “high”, while recreational varieties of marijuana have been cultivated to maximize the amount of THC for recreational purposes. For more information see:
Valerian is another great herb that's used as a sedative. Valerian (Valeriana officinalis) soothes anxiety and is often used as a sleep aid. Commonly doubled up with California poppy, it makes a powerful, but gentle sedative. Valerian can interact with medications and shouldn't be used without first checking with your doctor. Pregnant and lactating women shouldn't take valerian.
Iscador, also known as Mistletoe therapy (or Viscum album, Viscum album Loranthaceae, and European Mistletoe), is a proprietary formulation manufactured by Swiss medical company, Weleda. The use of mistletoe was pioneered by Rudolf Steiner, and was popularized in Europe, specifically Switzerland and Germany. Today, up to 60% of cancer patients in these European nations receive Iscador injections as part of their cancer treatment. The specialized therapy utilizes a purified mistletoe extract to kill cancer cells and simultaneously stimulate the immune system. One article from the Stram Center for Integrative Medicine notes:

Bee Balm was often used by the Native Americans to treat intestinal problems, colic and flatulence. Tea made from this plant was used to induce sweating and break fevers. Bee balm is often used to treat the common cold and sore throat as well. The leaves of this plant are a good source of essential oil that contains thymol. Thymol is an antibiotic and often used as an ingredient in mouthwash.
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